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ASVAB · General Science · 6 min read

Chemical Reactions, Acids and Bases

In this lesson you will
  • Distinguish between physical and chemical changes and apply the Law of Conservation of Mass to chemical equations.
  • Identify the five major types of chemical reactions by their patterns of reactants and products.
  • Explain the properties of solutions, solubility behaviors, acids, bases, indicators, and the pH scale.

Physical vs. Chemical Changes and Chemical Equations

In your everyday life and on the General Science subtest of the ASVAB, understanding how matter transforms is fundamental. A physical change alters the form or appearance of a substance without changing its chemical composition. Everyday actions such as tearing, crushing, cutting, and grinding are physical changes because they alter only the size and shape of the material. Similarly, phase changes, including melting, freezing, boiling, and condensing, are physical changes. Dissolving sugar or salt in water is also a physical change because the chemical identity of the substance remains unchanged.

In contrast, a chemical change results in the formation of one or more new substances with different chemical properties. Common real-world examples of chemical changes include rusting iron and burning wood. When a chemical reaction occurs, several possible signs may be observed: a color change, gas production, the formation of a precipitate, or a temperature change. A precipitate is an insoluble solid that forms in a solution, often when dissolved substances react. It is critical to remember that no single sign proves that a chemical reaction occurred.

All chemical changes follow the Law of Conservation of Mass, which states that matter cannot be created or destroyed in a chemical reaction. Because of this principle, the total mass of the reactants must equal the total mass of the products in any chemical reaction. Reactants are the starting substances in a chemical reaction and are written on the left side of the reaction arrow. Products are the new substances formed by the reaction and are written on the right side of the reaction arrow.

To represent this conservation on paper, scientists write chemical equations using subscripts and coefficients. Subscripts in a chemical formula show the numbers or ratios of atoms of each element. Because changing subscripts changes the chemical formula itself, you must never change them to balance an equation. Instead, coefficients, which are whole numbers placed before chemical formulas, are used to balance the number of each type of atom on both sides. A chemical equation is balanced when the number of atoms of each element is identical on both sides of the arrow.

Comparison of Physical and Chemical Changes
FeaturePhysical ChangeChemical Change
Chemical CompositionRemains completely unchangedForms new substances with different properties
Common ObservationsChanges in size, shape, or state of matterColor change, gas, precipitate, or temperature change
Everyday ExamplesMelting, boiling, crushing, tearing, dissolving salt or sugarRusting iron, burning wood
Exam tip. On the ASVAB, you cannot use a calculator. For practice without a calculator, use friendly numbers: if 10 grams of reactants react completely, the products have a total mass of 10 grams when all products, including any gases, are counted. Also, remember never to alter subscripts when balancing equations; only adjust the coefficients in front of the formulas.

Common mistakes

  • Changing the subscripts in a chemical formula instead of adjusting the coefficients when balancing a chemical equation.
  • Assuming that dissolving salt or sugar in water is a chemical change, when it is actually a physical change because the identity of the substance is unchanged.
  • Believing that a lower pH always indicates a stronger acid, when a lower pH simply means a higher hydronium-ion concentration in the solution.
  • Thinking that gases generally dissolve better in warm liquids, when warming a liquid generally decreases gas solubility.

Key points

  • A physical change alters form, size, or state without altering chemical composition, while a chemical change forms new substances with different chemical properties.
  • The Law of Conservation of Mass dictates that mass cannot be created or destroyed, requiring chemical equations to have equal numbers of each type of atom on reactant and product sides.
  • Five commonly taught reaction types are synthesis, decomposition, single replacement, double replacement, and combustion; combustion can be complete or incomplete.
  • A solution contains a solute dissolved in a solvent; heating increases the solubility of many, but not all, solids, while gas solubility generally decreases with heating and increases as the gas's pressure above the liquid rises.
  • Acids yield hydrogen or hydronium ions in water, while bases yield hydroxide ions in water.
  • At about 25°C, a pH below 7 is acidic, 7 is neutral (such as pure water), and above 7 is basic; each whole-number step reflects a tenfold difference in hydrogen ion concentration.
  • Neutralization occurs when an acid reacts with a hydroxide base, combining hydrogen ions and hydroxide ions to form water and a salt.

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Original lesson written for ASVAB practice · updated October 31, 2026. Exam names are trademarks of their owners; tests.global is not affiliated with them.